electrochemistry

Question: In which of the following cells will the emf be independent of the activity of the chloride ion



1) $Zn|ZnC{{l}_{2}}(aq)|Pt(C{{l}_{2}})$
2) $Zn|ZnC{{l}_{2}}(aq)||KCl(aq)|AgCl\,(s),\,Ag$
3) $Ag,\,AgCl\,(s)|KCl(aq)|Pt(C{{l}_{2}})$
4) $Hg,\,H{{g}_{2}}C{{l}_{2}}(s)|KCl(aq)||AgN{{O}_{3}}(aq)|Ag$
Solution: Explanation: No Explanation
Electrode potential Ecell Nernst equation and ECS

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